ZB 06 - Nanoelectrochemistry (W.Nogala)

H2O2 Generation at a Carbon-Paste Electrode with Decamethylferrocene in 2-Nitrophenyloctyl Ether as a Binder: Catalytic Effect of MoS2 Particles

Author(s): Jedraszko, Justyna and Krysiak, Olga and Adamiak, Wojciech and Nogala, Wojciech and Girault, Hubert H. and Opallo, Marcin
Title: H2O2 Generation at a Carbon-Paste Electrode with Decamethylferrocene in 2-Nitrophenyloctyl Ether as a Binder: Catalytic Effect of MoS2 Particles
Abstract: Here, we report hydrogen peroxide generation at the 2-nitrophenyloctyl (NPOE)/water interface with decamethylferrocene as an electron The progress of this reaction was detected by the observation of color change in the organic and aqueous phases in a series of experiments. The shape change in cyclic voltammograms at a carbon-paste electrode with decamethylferrocene in NPOE indicates a (electro)catalytic reaction. Hydrogen peroxide was detected at a Pt microelectrode tip positioned next to carbon-paste electrode. For this purpose, scanning electrochemical (SECM) approach curves were recorded. Analogous experiments the possibility of electrochemical regeneration of the donor. The (electro)catalytic effect of MoS2 on hydrogen generation was found by using both shake-flask and SECM experiments.
Pages: 1400-1406
Journal: CHEMELECTROCHEM
Publisher: WILEY-V C H VERLAG GMBH
Addres: POSTFACH 101161, 69451 WEINHEIM, GERMANY
Volume: 3
ID: ISI:000383623400016
Year: 2016
DOI: 10.1002/celc.201600242